Preheat the oven to 325°F (163°C). Line a 12-cup muffin tin with cupcake liners.
Combine Dry Ingredients: In a small bowl, whisk together the flour, baking soda, salt, cocoa powder, and espresso powder (if using). Set aside.
Make Chocolate Mixture: In a large bowl, whisk together the chocolate chips, boiling water, sour cream, vegetable oil, eggs, granulated sugar, and vanilla extract until smooth and well combined.
Combine Wet and Dry: Gradually add the dry ingredients to the wet ingredients and mix until smooth and no lumps remain.
Fill Cupcake Liners: Spoon the batter into the cupcake liners, filling each about 2/3 full. Bake for 18-22 minutes, or until a toothpick inserted into the center comes out clean. Allow the cupcakes to cool in the pan for 10 minutes, then transfer to a wire rack to cool completely.